Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI-D Analysis of a Novel Diaryltellurium Acetimidate

Mallow, Ole; Bolsinger, Jens; Finke, Pamela; Hesse, Malte; Chen, Yu-Sheng; Duthie, Andrew; Grabowsky, Simon; Luger, Peter; Mebs, Stefan; Beckmann, Jens

doi:10.7892/boris.138474

Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI-D Analysis of a Novel Diaryltellurium Acetimidate

BORIS DOI

10.7892/boris.138474

Date of Publication

2014

Publication Type

Article

Division/Institute

Departement für Chemi...

Author

Mallow, Ole
Bolsinger, Jens
Finke, Pamela
Hesse, Malte
Chen, Yu-Sheng
Duthie, Andrew
Grabowsky, Simon	Departement für Chemie und Biochemie (DCB)
Luger, Peter
Mebs, Stefan
Beckmann, Jens

Subject(s)

500 - Science::570 - ...

500 - Science::540 - ...

Series

Journal of the American Chemical Society

ISSN or ISBN (if monograph)

0002-7863

Publisher

American Chemical Society

Language

English

Publisher DOI

10.1021/ja505648x

Description

The reaction of the intramolecularly coordinated diaryltellurium(IV) oxide (8-Me2NC10H6)2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate (8-Me2NC10H6)2TeNC(O)CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(IV) chloride [(8-Me2NC10H6)2Te(OH)]Cl.

Handle

https://boris-portal.unibe.ch/handle/20.500.12422/185760

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Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI-D Analysis of a Novel Diaryltellurium Acetimidate

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