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Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI-D Analysis of a Novel Diaryltellurium Acetimidate

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cris.virtual.author-orcid0000-0002-3377-9474
cris.virtualsource.author-orcid48975b5a-fc75-4857-a723-b237d6161bbb
datacite.rightsrestricted
dc.contributor.authorMallow, Ole
dc.contributor.authorBolsinger, Jens
dc.contributor.authorFinke, Pamela
dc.contributor.authorHesse, Malte
dc.contributor.authorChen, Yu-Sheng
dc.contributor.authorDuthie, Andrew
dc.contributor.authorGrabowsky, Simon
dc.contributor.authorLuger, Peter
dc.contributor.authorMebs, Stefan
dc.contributor.authorBeckmann, Jens
dc.date.accessioned2024-10-28T18:15:26Z
dc.date.available2024-10-28T18:15:26Z
dc.date.issued2014
dc.description.abstractThe reaction of the intramolecularly coordinated diaryltellurium(IV) oxide (8-Me2NC10H6)2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate (8-Me2NC10H6)2TeNC(O)CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(IV) chloride [(8-Me2NC10H6)2Te(OH)]Cl.
dc.description.numberOfPages4
dc.description.sponsorshipDepartement für Chemie und Biochemie (DCB)
dc.identifier.doi10.7892/boris.138474
dc.identifier.publisherDOI10.1021/ja505648x
dc.identifier.urihttps://boris-portal.unibe.ch/handle/20.500.12422/185760
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.relation.ispartofJournal of the American Chemical Society
dc.relation.issn0002-7863
dc.relation.organizationDCD5A442C14DE17DE0405C82790C4DE2
dc.subject.ddc500 - Science::570 - Life sciences; biology
dc.subject.ddc500 - Science::540 - Chemistry
dc.titleOxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI-D Analysis of a Novel Diaryltellurium Acetimidate
dc.typearticle
dspace.entity.typePublication
dspace.file.typetext
oaire.citation.endPage10873
oaire.citation.issue31
oaire.citation.startPage10870
oaire.citation.volume136
oairecerif.author.affiliationDepartement für Chemie und Biochemie (DCB)
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unibe.date.licenseChanged2020-02-06 10:37:28
unibe.description.ispublishedpub
unibe.eprints.legacyId138474
unibe.journal.abbrevTitleJ AM CHEM SOC
unibe.refereedtrue
unibe.subtype.articlejournal

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