Oxygen Transfer from an Intramolecularly Coordinated Diaryltellurium Oxide to Acetonitrile. Formation and Combined AIM and ELI-D Analysis of a Novel Diaryltellurium Acetimidate

BORIS DOI
Publisher DOI
Description
The reaction of the intramolecularly coordinated diaryltellurium(IV) oxide (8-Me2NC10H6)2TeO with acetonitrile proceeds with oxygen transfer and gives rise to the formation of the novel zwitterionic diaryltelluronium(IV) acetimidate (8-Me2NC10H6)2TeNC(O)CH3 (1) in 57% yield. Hydrolysis of 1 with hydrochloric acid affords acetamide and the previously known diarylhydroxytelluronium(IV) chloride [(8-Me2NC10H6)2Te(OH)]Cl.
Date of Publication
2014
Publication Type
Article
Subject(s)
500 - Science::570 - Life sciences; biology
500 - Science::540 - Chemistry
Language(s)
en
Contributor(s)
Mallow, Ole
Bolsinger, Jens
Finke, Pamela
Hesse, Malte
Chen, Yu-Sheng
Duthie, Andrew
Luger, Peter
Mebs, Stefan
Beckmann, Jens
Additional Credits
Departement für Chemie und Biochemie (DCB)
Series
Journal of the American Chemical Society
Publisher
American Chemical Society
ISSN
0002-7863
Access(Rights)
restricted
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