The Significance of Ionic Bonding in Sulfur Dioxide: Bond Orders from X-ray Diffraction Data

BORIS DOI
Date of Publication
2012
Publication Type
Article
Division/Institute

Departement für Chemi...

Author
Luger, Peter
Buschmann, Jürgen
Schneider, Thomas
Schirmeister, Tanja
Sobolev, Alexandre N.
Jayatilaka, Dylan
Subject(s)

500 - Science::570 - ...

500 - Science::540 - ...

Series
Angewandte Chemie (International ed.)
ISSN or ISBN (if monograph)
1433-7851
Publisher
Wiley-VCH
Language
English
Publisher DOI
Description
A novel refinement technique for X‐ray diffraction data has been employed to derive S-O bond orders in sulfur dioxide experimentally. The results show that ionic S-O bonding dominates over hypervalency.
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