Kapat, AjoyAjoyKapatKonig, AndreasAndreasKonigMontermini, FlorianFlorianMonterminiRenaud, PhilippePhilippeRenaud0000-0002-9069-71092024-10-112024-10-112011https://boris-portal.unibe.ch/handle/20.500.12422/79675A one-pot procedure for the efficient hydroazidation of alkenes involving hydroboration with catecholborane followed by reaction with benzenesulfonyl azide in the presence of a radical initiator is described. The regioselectivity is controlled by the hydroboration step and corresponds in most cases to an anti-Markovnikov regioselectivity. This procedure is applicable to a wide range of alkenes and gives excellent results with 1,2-disubstituted and trisubstituted alkenes.enarticle00029524140003310.1021/ja2054989