Ehret, EdouardEdouardEhret0000-0002-2769-7624Iacovache, IoanIoanIacovacheLangenegger, Simon M.Simon M.LangeneggerZuber, BenoîtBenoîtZuber0000-0001-7725-5579Häner, RobertRobertHäner0000-0001-5014-43182025-04-222025-04-222025-03-28https://boris-portal.unibe.ch/handle/20.500.12422/208856The self-assembly of two isomeric amphiphilic cholane-phenanthrene-cholane trimers and the light-harvesting properties of the formed supramolecular assemblies in aqueous medium are presented. Distinct differences in the supramolecular nanostructures were observed based on the type of phenanthrene isomer used, as well as on the cooling rate applied during the thermal self-assembly process. A fast cooling rate resulted in the formation of 2D objects (nanosheets) with both trimers. In contrast, a slow cooling process resulted in the observation of 3D objects, with worm-like nanostructures for the self-assembled 3,6-disubstituted phenanthrene trimer and nanotubes for the 2,7-isomer. Upon doping with an acceptor chromophore, the supramolecular phenanthrene assemblies demonstrated efficient energy transfer. The presence of small quantities (6%) of a pyrene acceptor resulted in a five-fold increase in the quantum yield compared to the phenanthrene trimer alone, highlighting their potential as artificial light-harvesting complexes. This work underscores the versatility of amphiphilic phenanthrene derivatives as building blocks for light-harvesting supramolecular systems.enAmphiphilesEnergy transferLight-harvesting complexPhosphodiesterSupramolecular polymers600 - Technology::610 - Medicine & health500 - Science::540 - Chemistryarticle10.48620/873934015194510.1002/cbic.202500121