Lochner, MartinMartinLochner0000-0003-4930-1886Meuwly, MarkusMarkusMeuwlyWoggon, Wolf-D.Wolf-D.Woggon2024-10-232024-10-232003https://boris-portal.unibe.ch/handle/20.500.12422/127880Crown-capped iron(S−) porphyrins 1·H2O and 2·H2O and their corresponding Ba2+ complexes have been prepared as active site analogues of the resting state of cytochrome P450cam. cw-EPR studies and electronic structure calculations at the density functional theory (DFT) level of model systems suggest a functional role of the water cluster of P450cam.en500 - Science::570 - Life sciences; biology500 - Science::540 - Chemistryarticle10.7892/boris.6096110.1039/b302274a