Synthesis and reactions of two stereoisomeric 4.5.5.5 fenestranes with bridgehead substituents

Publisher DOI
Description
The [4.5.5.5]fenestranes 2 and 3 with two different functionalities were prepared in seven steps with overall yields of 5% and 10%, respectively. For introduction of a bridgehead double bond the removal of the tertiary hydroxy group was investigated in the two stereoisomeric hydroxyketones 12 and 15. Whereas the dehydration readily occurred in 12, a ring opening reaction was observed for 15. (C) 2011 Elsevier Ltd. All rights reserved.
Date of Publication
2011
Publication Type
Article
Language(s)
en
Contributor(s)
Weyermann, Philipp
Additional Credits
Series
Tetrahedron
Publisher
Elsevier Science
ISSN
0040-4020
Access(Rights)
metadata.only
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