A Radical Procedure for the Anti-Markovnikov Hydroazidation of Alkenes

Publisher DOI
Description
A one-pot procedure for the efficient hydroazidation of alkenes involving hydroboration with catecholborane followed by reaction with benzenesulfonyl azide in the presence of a radical initiator is described. The regioselectivity is controlled by the hydroboration step and corresponds in most cases to an anti-Markovnikov regioselectivity. This procedure is applicable to a wide range of alkenes and gives excellent results with 1,2-disubstituted and trisubstituted alkenes.
Date of Publication
2011
Publication Type
Article
Language(s)
en
Contributor(s)
Kapat, Ajoy
Konig, Andreas
Montermini, Florian
Additional Credits
Departement für Chemie und Biochemie (DCB)
Series
Journal of the American Chemical Society
Publisher
American Chemical Society
ISSN
0002-7863
Access(Rights)
metadata.only
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