Publication:
Chemical Bonding in Polarised Push-Pull Ethylenes

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cris.virtual.author-orcid0000-0002-3631-1535
cris.virtual.author-orcid0000-0002-8281-4264
cris.virtual.author-orcid0000-0002-3377-9474
cris.virtualsource.author-orcidc4026c58-a0b7-4e30-8cc7-431c73d0e010
cris.virtualsource.author-orcide185250f-e660-44eb-ad9c-a410845eac78
cris.virtualsource.author-orcid48975b5a-fc75-4857-a723-b237d6161bbb
dc.contributor.authorYanai, Hikaru
dc.contributor.authorSuzuki, Takumi
dc.contributor.authorKleemiss, Florian
dc.contributor.authorFukaya, Haruhiko
dc.contributor.authorDobashi, Yasuo
dc.contributor.authorMalaspina, Lorraine
dc.contributor.authorGrabowsky, Simon
dc.contributor.authorMatsumoto, Takashi
dc.date.accessioned2024-10-28T18:14:27Z
dc.date.available2024-10-28T18:14:27Z
dc.date.issued2019
dc.description.abstract1,1‐Diamino‐2,2‐bis(triflyl)ethylenes with both twisted and planar structures around the partial “C=C” bond were synthesised. Bonding properties in these compounds were analysed by an experimental approach using high‐resolution X‐ray diffraction data treated with X‐ray wavefunction refinement (XWR). In the twisted compound, a dominant contribution of the charge‐separated resonance structure was revealed. On the contrary, the nearly planar compound still showed π‐bonding character, however, with a considerable contribution of the charge‐separated resonance structure.
dc.description.numberOfPages6
dc.description.sponsorshipDepartement für Chemie, Biochemie und Pharmazie (DCBP)
dc.identifier.doi10.7892/boris.138388
dc.identifier.publisherDOI10.1002/anie.201904176
dc.identifier.urihttps://boris-portal.unibe.ch/handle/20.500.12422/185693
dc.language.isoen
dc.publisherWiley-VCH
dc.relation.ispartofAngewandte Chemie (International ed.)
dc.relation.issn1433-7851
dc.relation.organizationDCD5A442C14DE17DE0405C82790C4DE2
dc.subject.ddc500 - Science::570 - Life sciences; biology
dc.subject.ddc500 - Science::540 - Chemistry
dc.titleChemical Bonding in Polarised Push-Pull Ethylenes
dc.typearticle
dspace.entity.typePublication
dspace.file.typetext
oaire.citation.endPage8844
oaire.citation.issue26
oaire.citation.startPage8839
oaire.citation.volume58
oairecerif.author.affiliationDepartement für Chemie und Biochemie (DCB)
oairecerif.author.affiliationDepartement für Chemie, Biochemie und Pharmazie (DCBP)
oairecerif.author.affiliationDepartement für Chemie und Biochemie (DCB)
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unibe.date.licenseChanged2020-01-20 09:51:57
unibe.description.ispublishedpub
unibe.eprints.legacyId138388
unibe.journal.abbrevTitleANGEW CHEM INT EDIT
unibe.refereedTRUE
unibe.subtype.articlejournal

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