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  3. Major-Element Geochemistry and Fe3+/ΣFe of Metabasites
 

Major-Element Geochemistry and Fe3+/ΣFe of Metabasites

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BORIS DOI
10.48620/86418
Publisher DOI
10.1093/petrology/egae120
Description
Metabasites (metamorphosed mafic rocks) are crucial for understanding metamorphic and tectonic processes. Their preservation in exhumed orogenic belts from throughout Earth’s history and the diverse mineral assemblages they form under different pressure–temperature conditions make them valuable for studying metamorphic processes. This work compiles a database of 6186 major-element whole-rock analyses of metabasites from different metamorphic facies (low-grade, greenschist, blueschist, amphibolite, granulite, and eclogite). These are used to explore the range and variability in their composition and assess geochemical differences among metamorphic facies. To mitigate the impact of outliers, median values and median absolute deviations (MAD) are used as measures of central tendency and dispersion. Metabasites show decreased volatile content with increasing metamorphic grade and generally consistent major-element contents across facies, with subtle differences interpreted to result from sampling bias. The median worldwide metabasite is as follows (anhydrous, normalised values in wt %, ±MAD): SiO2 = 51.36±3.40, TiO2 = 1.33±0.82, Al2O3 = 15.47±1.97, FeOtotal = 11.48±2.50, MnO 0.20±0.06, MgO = 6.83±2.25, CaO = 9.84±2.34, Na2O = 2.82±1.05, K2O = 0.50±0.61, and P2O5 = 0.18±0.16. The median XMg = MgO/(MgO+FeOtotal) is 0.51±0.09. The median Fe3+/ΣFe was measured by titration in 3153 samples and is 0.26±0.12, comparable to values in altered oceanic crust or arc basalts. Future research must carefully examine the distribution of Fe3+ amongst minerals in metabasites, allowing for a better evaluation of the median whole-rock Fe3+/ΣFe and its potential susceptibility to analytical interferences.
Date of Publication
2024-11-08
Publication Type
Article
Language(s)
en
Contributor(s)
Forshaw, Jacob B.
Institute of Geological Sciences, Petrology
Institute of Geological Sciences
Dominguez, Hugo
Institute of Geological Sciences, Petrology
Institute of Geological Sciences
Markmann, Thorsten A.
Institute of Geological Sciences, Petrology
Institute of Geological Sciences
Tamblyn, Renée
Institute of Geological Sciences, Petrology
Institute of Geological Sciences
Hermann, Jörgorcid-logo
Institute of Geological Sciences, Petrology
Institute of Geological Sciences
Riel, Nicolas
Lanari, Pierreorcid-logo
Institute of Geological Sciences (GEO) - Computational Petrology and Geochemistry
Institute of Geological Sciences
Additional Credits
Institute of Geological Sciences
Institute of Geological Sciences, Petrology
Institute of Geological Sciences (GEO) - Computational Petrology and Geochemistry
Series
Journal of Petrology
Publisher
Oxford University Press (OUP)
ISSN
0022-3530
1460-2415
Access(Rights)
open.access
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