• LOGIN
Repository logo

BORIS Portal

Bern Open Repository and Information System

  • Publication
  • Projects
  • Funding
  • Research Data
  • Organizations
  • Researchers
  • LOGIN
Repository logo
Unibern.ch
  1. Home
  2. Publications
  3. A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting
 

A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting

Options
  • Details
BORIS DOI
10.7892/boris.138440
Date of Publication
2017
Publication Type
Article
Division/Institute

Departement für Chemi...

Author
Bulut, Aysun
Wörle, Michael
Zorlu, Yunus
Kirpi, Erdogan
Kurt, Huseyin
Zubieta, Jon
Grabowsky, Simonorcid-logo
Departement für Chemie und Biochemie (DCB)
Beckmann, Jens
Yücesan, Gündoğ
Subject(s)

500 - Science::570 - ...

500 - Science::540 - ...

Series
Acta crystallographica Section B
ISSN or ISBN (if monograph)
2052-5206
Publisher
International Union of Crystallography
Language
English
Publisher DOI
10.1107/S2052520617000245
Description
The reaction of appropriate copper and vanadium salts with tetratopic methane tetra-p-phenylphosphonic acid (MTPPA) in the presence of 2,2':6':2''-terpyridine (terpy) yielded the three-dimensional bimetallic copper vanadium phosphonate framework [{Cu(terpy)}4Cu(VO2)4(MTPPA-H)2]·4H2O (1). Terpy has no net contribution to the three-dimensional structure providing a potential platform for void space formation via mold-casting. The structure was characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). Magnetic measurements were performed using a SQUID magnetometer. The crystal structure of the methanol solvate of the free ligand, MTPPA·MeOH, was analysed using Hirshfeld surfaces and fingerprint plots.
Handle
https://boris-portal.unibe.ch/handle/20.500.12422/185735
Show full item
File(s)
FileFile TypeFormatSizeLicensePublisher/Copright statementContent
041_Bulut2017_ActaB.pdftextAdobe PDF1007.92 KBpublished
BORIS Portal
Bern Open Repository and Information System
Build: 360c85 [14.04. 8:05]
Explore
  • Projects
  • Funding
  • Publications
  • Research Data
  • Organizations
  • Researchers
More
  • About BORIS Portal
  • Send Feedback
  • Cookie settings
  • Service Policy
Follow us on
  • Mastodon
  • YouTube
  • LinkedIn
UniBe logo