A potential Cu/V-organophosphonate platform for tailored void spaces via terpyridine mold casting
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BORIS DOI
Date of Publication
2017
Publication Type
Article
Division/Institute
Author
Bulut, Aysun | |
Wörle, Michael | |
Zorlu, Yunus | |
Kirpi, Erdogan | |
Kurt, Huseyin | |
Zubieta, Jon | |
Beckmann, Jens | |
Yücesan, Gündoğ |
Series
Acta crystallographica Section B
ISSN or ISBN (if monograph)
2052-5206
Publisher
International Union of Crystallography
Language
English
Publisher DOI
Description
The reaction of appropriate copper and vanadium salts with tetratopic methane tetra-p-phenylphosphonic acid (MTPPA) in the presence of 2,2':6':2''-terpyridine (terpy) yielded the three-dimensional bimetallic copper vanadium phosphonate framework [{Cu(terpy)}4Cu(VO2)4(MTPPA-H)2]·4H2O (1). Terpy has no net contribution to the three-dimensional structure providing a potential platform for void space formation via mold-casting. The structure was characterized by single-crystal X-ray diffraction and thermogravimetric analysis (TGA). Magnetic measurements were performed using a SQUID magnetometer. The crystal structure of the methanol solvate of the free ligand, MTPPA·MeOH, was analysed using Hirshfeld surfaces and fingerprint plots.