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  3. Allgemeiner Zugang zu Polyaminen mit Ethan-1,2-diamin-Einheiten: Synthese von nicht natürlich vorkommenden homologen und isomerenN1,4-Di(4-cumaroyl)sperminen
 

Allgemeiner Zugang zu Polyaminen mit Ethan-1,2-diamin-Einheiten: Synthese von nicht natürlich vorkommenden homologen und isomerenN1,4-Di(4-cumaroyl)sperminen

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BORIS DOI
10.7892/boris.60965
Date of Publication
December 1998
Publication Type
Article
Division/Institute

Departement für Chemi...

Author
Lochner, Martinorcid-logo
Departement für Chemie und Biochemie (DCB)
Geneste, Hervé
Hesse, Manfred
Subject(s)

500 - Science::570 - ...

500 - Science::540 - ...

Series
Helvetica chimica acta
ISSN or ISBN (if monograph)
0018-019X
Publisher
Verlag Helvetica Chimica Acta
Language
English
Publisher DOI
10.1002/(SICI)1522-2675(19981216)81:12<2270::AID-HLCA2270>3.0.CO;2-%23
Description
The synthesis of the three N,N′-di(4-coumaroyl)tetramines, i.e., of (E,E)-N-{3-[(2-aminoethyl)amino]propyl}-3,3′-bis(4-hydroxyphenyl)-N,N′-(ethane-1,2-diyl)bis[prop-2-enamide] (1a), (E,E)-N-{4-[(2-aminoethyl)amino]butyl}-3,3′-bis(4-hydroxyphenyl)-N,N′-(ethane-1,2-diyl)bis[prop-2-enamide] (1b), and (E,E)-N-{6-[(2-aminoethyl)amino]hexyl}-3,3′-bis(4-hydroxyphenyl)-N,N′-(ethane-1,2-diyl)bis[prop-2-enamide] (1c), is described. It proceeds through stepwise construction of the symmetric polyamine backbone including protection and deprotection steps of the amino functions. Their behavior on TLC in comparison with that of 1,4-di(4-coumaroyl)spermine (=(E,E)-N-{4-[(3-aminopropyl)amino]butyl}-3,3′-bis(4-hydroxyphenyl)-N,N′-(propane-1,3-diyl)bis[prop-2-enamide]; 2) is discussed.
Handle
https://boris-portal.unibe.ch/handle/20.500.12422/127883
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2270_ftp.pdftextAdobe PDF163.84 KBpublisherpublished restricted
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