Thermal and near-infrared light induced spin crossover in a mononuclear iron( ii ) complex with a tetrathiafulvalene-fused dipyridophenazine ligand
Publisher DOI
Abstract
A mononuclear Fe(II) complex involving a tetrathiafulvalene-based ligand exhibits thermal spin-crossover (around 143 K) with pronounced hysteresis behaviour (48 K). The chromophoric and π-extended ligand allows Near-Infrared (NIR) sensitization for the light-induced excited spin-state trapping (LIESST) with T(LIESST) = 90 K.
Date Issued
2016
Publication Type
Article
Subject(s)
Language(s)
en
Author(s)
Pointillart, F. | |
Liu, X. | |
Kepenekian, M. | |
Le Guennic, B. | |
Golhen, S. | |
Dorcet, V. | |
Roisnel, T. | |
Cador, O. | |
You, Z. | |
Ouahab, L. |
Additional Credits
Journal
Dalton transactions
Publisher
Royal Society of Chemistry
ISSN
1477-9226
Access(Rights)
open.access