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  3. Optical and scintillation properties of CsBa2I5:Eu2+

Optical and scintillation properties of CsBa2I5:Eu2+

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DOI
10.7892/boris.59698
Publisher DOI
10.1016/j.jlumin.2013.08.058
Abstract
The scintillation and luminescence properties of pure CsBa2I5 and CsBa2I5 doped with 0.5% Eu and 5% Eu were studied between 78 K and 600 K. Single crystals were grown by the vertical Bridgman method from the melt. CsBa2I5:5% Eu showed a light yield of 80,000 photons/MeV, an energy resolution of 2.3% for the 662 key full absorption peak, and an excellent proportional response. Two broad emission bands centered at 400 nm and 600 nm were observed in the radioluminescence spectrum of pure CsBa2I5. The Eu2+ 5d-4f emission band was observed at 430 nm. The radiative lifetime of the Eu2+ excited state was determined as 350 ns. With increasing temperature and Eu concentration the Eu2+ emission shifts to longer wavelengths and its decay time lengthens as a result of self-absorption of the Eu2+ emission. Multiple thermoluminescence glow peaks and a sharp decrease of the light yield at temperatures below 200 K were observed and related to the presence of the charge carrier traps in CsBa2I5:Eu.
Date Issued
2014
Publication Type
Article
Subject(s)
500 Science > 540 Chemistry
Language(s)
en
Author(s)
Alekhin, Mikhail S.
Biner, Daniel  
Departement für Chemie und Biochemie (DCB)  
Krämer, Karl  
Departement für Chemie und Biochemie (DCB)  
Dorenbos, Pieter
Additional Credits
Departement für Chemie und Biochemie (DCB)  
Journal
Journal of luminescence
Publisher
North-Holland
ISSN
0022-2313
Access(Rights)
restricted
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